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Angelina Jolie posing for the camera.

A Look Back At Angelina Jolie’s Past Marriages

Gettyimages | Kevin Winter
By Jordan White

Remember “Brangelina?” Well, it turns out, Brad Pitt wasn’t Angelina Jolie’s first husband.

The couple, who met while filming “Mr. & Mrs. Smith,” started dating in 2005 and married in 2016, before splitting up two years later. They share six children, three of whom they adopted.

Their romance has been well-publicized over the years. Partly because they fall in love while Pitt was still married to Jennifer Aniston.

Before Pitt and Jolie became one of Hollywood’s favorite couples, the actress was linked to several other celebrities. In fact, she married a few of them!

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Jonny Lee Miller

Jonny Lee Miller on set holding a thumbs up finger.
Jonny Lee Miller/Instagram

Jolie met actor Jonny Lee Miller in 1995, and the two started dating shortly after. During their relationship, the actress also dated model Jenny Shimizu who she met on the set of “Foxfire” in 1996.

In March 1996, Jolie and Lee Miller married. At the time, Jolie was only 20-years-old.

A year after they married, Jolie discussed her relationship with Shimizu saying, "I probably would have married Jenny Shimizu if I hadn't married my husband."

She added, "I fell in love with her the first second I saw her." In 2000, Jolie and Lee Miller divorced.

Billy Bob Thornton

Angelina Jolie and Billy Bob Thornton posing together at an event.
Gettyimages | Vince Bucci

In 1999, Jolie and Billy Bob Thornton started dating after meeting on the set of “Pushing Tin.”

At the time, the actor was engaged to Laura Dern. However, Thornton left Dern for Jolie and the two got married.

Their relationship was very publicized and unique. The two reportedly wore vials of each other's blood around their necks.

During their marriage, Jolie adopted a child named Maddox as a single parent. Thornton, who had children from previous relationships, didn’t end up adopting him.

In 2002, the couple separated and their divorce was finalized the following year.

Brad Pitt

Blurry picture of Angelina Jolie and Brad Pitt walking outside.
Wikimedia | https://commons.wikimedia.org/wiki/File:Jolie-Pitt_-_Blood_and_Honey_set.jpg

Between 2003 and 2004, Jolie reportedly had flings with several of her “Alexander” co-stars. She was linked to Colin Farrell, Jared Leto, and Val Kilmer.

In 2004, while filming “Mr. & Mrs. Smith” Jolie and Pitt met and fell in love. At the time, Pitt was still married to Jennifer Aniston. In January 2005, Pitt and Aniston announced their separation after a five-year marriage.

A few months later, Pitt and Jolie were spotted vacationing together. That same year, the actor adopted her son, Maddox.

Brad Pitt talking during an interview.
Wikimedia | https://commons.wikimedia.org/wiki/File:Brad_Pitt_(15408493447).jpg

In July 2005, Jolie adopted another child, Zahara, who Pitt eventually adopted as well. In January 2006, the two announced they were expecting.

Throughout their long-term relationship, the couple adopted another child and gave birth to twins.

In 2012, Jolie confirmed the two were engaged. Two years later, they married in France with all their children apart of the ceremony.

Sadly, in August 2016, Jolie filed for divorce.

Since there split, there’s been speculation Pitt is in a relationship with Alia Shawkat. The news broke after the two were spotted spending time together.

However, neither Pitt or Shawkat has confirmed the rumors.

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